Galvanic battery and apparatus connected therewith



I' 44 Sheets-Sheet 1, i A. R. UPWARD 8a C .'W.PRIDH'AM. GALV-ANIG BATTERY AND APPARATUS CONNECTED THBREWITH.

(No Model.)

Patented Peb. 1/5,

M anni RRR Sheets-Sheet 2. A. R'. UPWARD 8v- C. W. PRIDHAM. GALVANIG BATTERY AND APPARATUSCONNBGTED THEREWITH.

' `l\To.v35"7,646.

(No Model.)

Patented Feb. 15, 1887,

(No Model.) `4 sheets-sheet s.

A. R. UPWARD 8v C. W..PRDHAM. GALVANIG BATTERY AND APPARATUS CONNECTED TEEEEWITH.

' No. 357,646." Patented'feb. 15,1887.

//v/////////// A Y////////./

gig-

(NoModel.) .Y 1 l 4sheets4-sheen4.

- `A. R. UPWARD 8v C. ,W. PRIDHAM. l GALVANI BATTERY AND 'APPARATUS' CONNECTEDTHBRWITH.

m1351646. Patentedhb. 15, 1887.

UNITED STATES PATENT OFFICE.

ALFREDRN UPWARD, OF WEST KENSINGTON, AND CHARLES WILLIAM PRIDHAM, on KENSINGTON, COUNTY OEMIDDLESEX, ENGLAND;

" GALVANIC BATTERY AND APPARATUS cloNNecTE'D Tl-lenewl'l'u.v

. SPECIFICATION formingpart of Letters Patent No. 357,646. datei'ebruary 15,'188T.

Application filed October 12, 1885. Serial' No. 179,689. (Nomodel.) latcntel in EnglandNovember 26. 1.884, No. 15.567, June 18. 1885, No. 7,461, and August 4, 1885, No. 9,302,- m France March 2, 1885, No. 174,503; in Spain August 31, 1886, No. 9,290, and

in Belgium October 6, 1886, No. 74,745.

v To all whom. ima/y concern:

'of' which the following is a specification, and

for which welhave obtained Letters Patent in GreatlBritain, No. 15,567, dated November 26, i '1884, N 0.7 ,461 ated June 18, 1885, and No.. 19,302, dated August 4, 1885; in France, No.

174,503, dated March, 2, 1885; in" Spain, No.

9,290, dated August 31, 1886, and in Belgium,

No. 74,745, dated October 6, 1886.

This invention has for its object improvements in galvanic batteries and `in apparatus connected therewith. Y

The improved battery is maintained in an active condition by the passage of chlorine gas into the cells. The gas is supplied from a gas-holderA of a special sort, and it is drawn through the battery by suction. The passage of the gas is controlled by an electric governor. Such a battery will be found very constant'and of great electro-motive force.

In the annexed drawings, Figure 1 is a vertical section, and Fig. 2 is a transverse section, ofV a battery -cell constructed in accordance with our invention. Fig. 3 is an elevation of algas holder or receiver. 1 section oi" a chlorinegenerator; Fig. 5, aver- Fig. 4 is-a vertical tical section of an aspirator, and Fig. 6 a diagram of electrical governing apparatus.l

a isl the outer cell or'vessel. It may be of glazed earthenware. v

b b are `inner cells of unglazed earthenware.

- c `c c are three carbon slabs,which are placed in the outer vessel, one on either side of each of the porous cells b b. The remaining space between the vessels a and b is then packed Y with carbon broken to a size to pass through a sieve with six holes to the linear inch. This carbon, which should be free from dust, is

thoroughly moistened before it is pnt into itsplace;-but any surplus liquid is drained olV fromV theV cell, so as to'leave it free for the c irculationof the gas.

Near the bottom of the cell is a socket, d', to receive a lead pipe to lead 'the gas into the cell. A glass tube, d, is also provided for the exit of the gas.

e represents cement, which is now applied to seal the top of the vessel c and to closel the space between the upper edges of the vessels a, and b. The cement which I prefer to employ consists of a mixture of equal parts of marine glue and pitch. The melted composition isv poured into the cell whichk it is required to seal. The surfaces Vto which the cement is required to adhere should be quite dry and rough. The joint is finished by carefully remelting the surface of the cement witha blowpipe iiame or in lother convenient manner. Thevessels b b are left open at the top, and each` receives a zincl element, j'. Vhen the battery is at work, the cells b are filled with liquid around the zinc element. Vater may be employed; but -a solution of chloride of zinc or of common salt is preferred.

In place of zinc as the anode, we may employ another metal-as, for-example, iron.

c c c and ff are wires'or conductors by which the current'is taken off. They may be connected with the elements in any convenient manner. Usually I castthe zinc f upon a wire whichhas previously been galvanized or tinned, and I make the connections with .the carbone by depositing copper uponvthem and then soldering the conductor to the metal so deposited, orby casting a leaden cap on the end of the carbon;

g is a stop-cock to draw o any liquid which may accumulate in the cell a.' Inconsequence of the chloride-of-zinc solution finding its way through the sides of the porous cell b, this liquid should be removed when it rises above the stop-cock g. A convenient way to dothis automatically is toallow the nose of the cock to dip down into a trough or vessel vfilled with the liquid. VThe cell a will then be automat-y ically voided of liquid, while the gas cannot escape.` The stop-cock g thenneed'never be 5 the stop-.cock g. The solution in the cells b' around the zinc should be kept between the specific gravity 1.2 and 1.4. If it tends to get stronger, as may sometimes happen, some, of

the solution should be removed from the open xo cells b and water added in its place.

The cells are coupled together in 'the usual way to form a batterywith any required num-- ber of elements.

The sockets d and the tubes d of the several x 5 cells are also connected together by lead pipes. The ends of the glass tubes are made taper, and are inserted into the coned ends of the leaden pipes. The joint is made tight with marine glue. In the samefway a tight joint is zo made aroundthe pipe in thesocke't d; or the connections may be made by other convenient appliances. Theseconnectiions may beso made that gas admitted at one end of the battery may travel continuously forward from cell to 2 5 cell until it reaches the other end of the battery; or, if the cells be numerous, the connections may be so made that gas may enter the battery at several dierent points. The chlo rine gas for use in the battery may be prepared inany convenient way, and it may be stored in a compressed state. The gas for immediate use is drawn from a gas-holder, which consists ofa column of a capacity slightly :in excess of the 'quantity of gas it is desired to 3 5 store. It should be lofty, say twenty feet or more in height, according to the scaleon which the apparatus is constructed. The column may be of yany material. which is not liable to be destroyed by the gas. .ilifellglazedv drain- 40 pipes built upwith marine glue between the anges aresuitable. In some cases the column :may be iilled with broken fragments of carbon or pebbles; or more or less divided by .par-

titions, to prevent adrnixture with air.

The column has a coverat the top,which is fitted with a long exit-tube of small diameter, by which means the column can be illed nearly to the top without much loss of gas.

The inlet for the gas from thegenerator or other sourcelof supply is nea-r the bottom, and so also is the outlet by which the gas passes vte the battery or batteries. One such store-vessel may be employed to supply a' nnmberof batteries. Chlorine gas being considerably heavier than air remains at the bottom of the gas-holder andmixes but littlewith the air, and such admixture as occurs is in no way detrimental to the action ofthe batteries to which the gas is supplied.

Sometimes we employ several gas-receiving columns connected in series, asis indicated in Fig. 3. There three columns are shown.; but as many as six may advantageously be employed, each consisting, say, of seven earthenware pipes nine inches in diameter and twentyfour inches long. They are well glazed on the inside and are put together with gas-tight `may be with Portland cement. Euch column is furnished at the top with a descending pipe, g', serving to connect one column with another. The last column of the series may be, however, entirely open at the top. In any case there is a passage by which air can enter or escape freely.

h is the pipe by which the gas arrives at the receiver, and a branch from the same pipe passes to the cells to feed them as they require. The pipes g connect the top of one column to the bottom of the next throughout the series.

whitened ata-the back, are introduced,in which the charge of gas can be seen, the color of the gas rendering it clearly visible. Thus when the r'st column is full the gas is seen in the lvessel tilowng from the first to the second `column, and so on, as each column fills. When the fifth column is full it is time to lessen the production of gas by cooling the generator. Similarly, when the production of gas is proceeding slowly,- or is intermitted,vthe progressiveemptying ofthe columns can be observed in the vessels e', the color disappearing progressively as an inflow of air at the far end of the series sweeps the chlorine before it from column to columntoward the battery-cells. We interpose, also, a glass vesselsimilar to i between the generator and the rst column; butin this vessel Awe place a little water. and the pipe from the generator just dipsv into this water. The object in 'this case is that the bubbling of the gas through the water may indicate the activity of the generator.

In working the apparatus it is often couvenient to employ a weighted charge in the generator, so roportioned to the capacity of the receiver t at it will4 till it without waste.

For the generation of the chlorine gas, it is eonvenient to employ a retort immersed in a waterbath. The retort is charged, as usual, with common salt,oxid e of manganese, and sulphuric acid. The liberation ofthe gas is promoted by heating the water-bath to the boilingpoint by a gas-flame beneath, or otherwise.-

The generator represented by Fig. 4 of the drawings consists of astoneware vessel, a. It is to beset within an exterior vessel, b', containing water, which is kept heated while the generator is at work. l

` a? is an aperture at the top of the vessel for introducing the charge of oxide of manganese and mnriatic acid in the usual proportions.

td'is a water-trap around the aperture a.

c2 is a movableleaden dome, and c3 is a pipe connectedwith the dome,'by which the gas is led away'to the receiver. When the dome is trap a3. A

d'l is a water-pipe connected with the vessel a'. It is intended to supply water to wash away the residue when the charge is expended, so that it may be got rid of without lifting the vessel a from its place,whieh would be troublesome on account of the weight of the vessel,

joints made with pitch and rnarincglue, or it' In the-course of these'pipes glass vessels Ii,

IOO

in place its edges dip into the water in the `The aspirator shown by Fig. 5

and also without lifting the dome c2 before the vessel is empty, as inconvenience would in that case result from escape of gas.

` In the use of this generator the heat of the water bath causes the gas to be liberated more or less rapidly, according to the temperature hours the charge is expended.

The apparatus is cleared out ready to receive another charge by opening the cock c,

connectedwth an opening inthe bottom of the vessel a', and with a drain the residue is then run off without smell, and the vessel a is afterward completely cleared by opening the water-tap d2. The gas passing oi by the pipe cs is taken to the gas-receiver;

In place of charging the vessel bf with water, sand or other slow conductor of heat may be employed.

At the outlet from eachbat-tery we provide a suction apparatus orv aspirator. Such an apparatus as is employed .in chemical laboratories to facilitate filtration, and in which air is with- -drawn by the operation of water descending a pipe under the influence ot' a head and of gravity, is suitable.

known construction and in common use in chemical laboratories.. It 'consists of a glass pipe of, say, three-eighths of an inch internal diameter and drawn out to a tapering end with,

say, one-eighth of an inch aperture or less.

W'ater from a main or cisteriris supplied to it and issues in a jet. The water-jetis delivered into lthe mouth of another pipe, which it descends vertically for some distance. The

mouth ofthe latter pipe receives the drawnout extremity ofthe jet-pipe, leaving a narrow annulan'passage all around. The descend-- ing pipe is taperedfrom the upper end down- Q ward for a short dist-ance, and below the tapering part it maybe ofthe same diameter as the pipe connected with the watermain. rlhe jet and the receiving-mouth are within an eggshaped inclosure of glass, and with this the battery-cellsare connected. The .descending pipe is usually bent at its lower end with two right-angle bends, which break the descent of 4the water. The gas thus 4drawn into the battery-cells operates in the following manner: The zinc plate is immersed in a solution of some' chloride. (such as sodium-chloride or common salt, which may ofcourse be used over and over again, andthe carbon is surrounded by free chlorine gas. Now, when the circuit is closed the chlorine of the chloride of sodium is free to act on the zinc or anode, on account.

of the free chlorine surrounding t-he carbon or cathode. 'The electro-motive force of this cell is high, on account of chlorine being an eleinentary substance.

g By arranging cells according `tothe details giventhe great disadvantage ot" having chlorine acting on the zinc with generation of waste heat is entirelyavoided. 4

We maintain the current from Ieach battery is of en ries of battery-cells.

constant while the battery is in use by providing anelectric governor in the circuit-an electric governor such as is usual with steam-engines driving dynamos to control the supply of steam, and consequently the speed of the l enginein accordance with the current passing. mam-tained, and the gas passes off until in some in thecircuit or of the difference of potential between the parts ot` this circuit, is suitable. The governor, in place of controlling a steamvalve, as whenY asteam-engine is governed, controls the water-valve of the suction appa ratus, and so increases or diminishes the Ilow ofgas thro`ugh the battery-cells in such manner as to maintain a constant current in the circuit or a constant dii-ference of potential beplace a small cistern in which isa fioat. There is an outlet near the bottom of the cistern, and itis connected with a pipe which dips down into a mercurycnp. The mercury-cup is supported on one end of a scale-beam, and

at the other end of the scale-beam the core of a solenoid hangs suspended within a solenoidcoil. 'Vhen no current is passing, the weight of the mercury-cup preponderates and the ou tlet from the cistern remains open. When the current from the battery passes through the coil, and when the ilow is sui'licient, the core is drawn down and the mercury-cup israised,

closing the outlet-pipe, and water is retained inthe cistern. The llo-.tt then rises. It moves the water-tap and cuts off the supply to the aspirator, leaving only a very small tiow. Little or no chlorine gas is then drawn from the receiver, and the electric current soon commcnces to decrease. The mercury-cup then again falls away, the outflow tro'm the cistern recommences, and the iioat descending sets the aspirator again to work.

The aspirator described will be found suitable for a series of,'say, twenty cells of two gallons capacity, this series being connected at one-end with the gas-receiver and at the other end with the aspirator. The solenoid and core and other parts of the electric governor are so adjusted as to permit the escape of water from the cistern somewhat before the battery comes'up toits maximum, and thenno gas is drawn te waste from the end of the se- The aspirator and governor should be fixed solidly against a wall.

, In cellsof large size with broad passages, gravity and the suction of the cell itself may be depended on to canse the chlorine gas to descend from thc gas-reeeiveiwto supplythe place of that which Venters into combination with the zinc; or the valve controlled by the governor may be a valve admitting air tothe IOC IIO

battery-cells to Amingle with the chlorinegas.

In this case, the suction being constant and the current through the cells constant, or nearly so, itwill be more or less rich in chlorine, ac-

cording to the position in which the air-admission valve is placed bythe governor. The

4L esatte" operation of the battery will be controlled and moderated accordingly. The air employed for this purpose may he drawn from the upper part of the gas-holder, and if this air has become to some extent impregnated with chlorine the gas will so be turned to account and Waste avoided.

1We are aware of English Patents No. 2003 of 1853, and No. 108 of 1883, and of United States Patent to Cheever, No. 233,601, of October 26, 1880. We do not, therefore7 claim anything shown in these patents.

fhat we claim isf- 1. A battery in which the carbon elements are contained in compartments which are kept void of liquid and filled with free uncombined chlorine gas. J

2. A batterycell in which azinc elementis immersed in a solution of a soluble chloride separated by a porous diaphragm from a coinpartment kept void of liquid but filled with free uncoxnbiued gaseous chlorine.

3. In a galvanic battery, the combination of the outer casing, the positive and negative elements, the granulated filling. the cement/'covering the top of the filling, and the inlet and outlet openings in the casing, and the free uncombined chlorine gas that 'passes-through the granulated lling which'surrounds the carbon element.

4. The combination of a chlorine battery with suction apparatus by lwhichthe gas is drawnforward through the battery-cells.

5. The combination o'f a chlorine-battery, an electric governor, and a suction apparatus, the said governor controlling the quantity ofgas drawn into the battery-cells by the suction apparatus.

6l The combination, with the cells of a gasbattery, of an open gas receiver or reservoir of 4o relatively vgreat height or length, supplying chlorine into the cells by suction, whether the suction he artificial or resulting from the ab Sorption of the gas within the cells. v

ALFRED RN UPWARD.

CHARLES WILLIAM PRIDHAM.

Witnesses:

JNO. DEAN, THOMAS LAKE,

Both of 17 Gracechurch St., London. 

